TitleTitanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands
Publication TypeJournal Article
Year of Publication2017
AuthorsBrown, A, Saber, M, Van den Heuvel, W, Schulte, K, Soncini, A, Dunbar, KR
JournalInorganic Chemistry
Volume56
Pagination1031-1035
Abstract
The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.
URLhttps://doi.org/10.1021/acs.inorgchem.6b02643
DOI10.1021/acs.inorgchem.6b02643
Library 
Soncini Group