Title | Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands |
Publication Type | Journal Article |
Year of Publication | 2017 |
Authors | Brown, A, Saber, M, Van den Heuvel, W, Schulte, K, Soncini, A, Dunbar, KR |
Journal | Inorganic Chemistry |
Volume | 56 |
Pagination | 1031-1035 |
Abstract | The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.
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URL | https://doi.org/10.1021/acs.inorgchem.6b02643 |
DOI | 10.1021/acs.inorgchem.6b02643 |
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